Title of the Paper Essays (433 words) - Communication,

Title of the Paper (Cultivating Communication Competence ) Submitted By ( Kadeejah Johnson, [emailprotected] ) Number and Name of Course (Oral Communication - COMM 101) Class Meeting Time/Day (M/W/F: 9:00 A.M. - 9:50 A . M. ) Professor (Dr. Ephraim Okoro) Semester (Fall 2016) Today's Date (Monday December 5 , 2016) Bowie State University Department of Communications Bowie, Maryland Meeting your girlfriend's parents for the first time is a big step in a relationship. You're taking it up a notch from casual dating; you're saying that you're ready to start solidifying your couple hood by placing yourself inside of her social and familial circle and allowing them to put a face to the name. You're ready to announce your interest in a lady to the most important people in her life. Thus, the experience can be a tad nerve racking. Parents are protective of their daughters. They want to feel comfortable with the idea of you as a boyfriend, as possibly the future man in her life. A boyfriend can make a woman completely happy or totally wreck her life, and they want to know that it's the former. And on the flip side, your girlfriend wants her family to like you. She wants you to shine so she can get their approval. And if she's hoping for a long-term relationship with you, she's got her fingers crossed that you'll get along with them. So, that's a lot of pressure. You' re a man and you're cool under pressure, but to have that kind of confidence you should prepare. I would encourage her that it is okay to meet my parents so that they are aware of who I have been spending much of my time with. Although it may come as a surprise I would ensure her that the best way for us to move forward is to look forward to the future. In communication studies, it is essential to know fundamentalknowledge about communication and its elements to be an effective and competent communicator. In communication, listening and interpersonal and intercultural skills are necessary tools that every communicator must have so that good communication and interaction will develop and emerge. Listening is a fundamental element in communication because this is the first step where communication messages and information are received and processed by the communicator. That is why when this instance takes place we can talk about it in a way that allows there to be ambiguity.

Black Rain essays

Black Rain essays The symbolization of bamboo spears and the situation during the Hiroshima bombing In the novel, Black Rain, by Masuji Ibuse, the bamboo spears symbolize the situation that the Japanese were in during the Hiroshima bombing. The Japanese have many traditions and just because their country is at war, does not mean that they should stop these traditions and give up all of their symbols of honor, pride, and dignity. During the war, one such symbol of honor or active duty was the bamboo spears. These bamboo spears that the village headman speaks of while giving an official send-off to the Young Mens Association are as he says, those symbols of your invincible determination to fight on to the bitter end your bamboo spears (13). He explains to these young men that the bamboo spears they hold should not be dropped until the end has come in such a way as if he was a Caesar leading his troops into the battle of Carthage. He glorifies these bamboo spears and the village headman never states what is this astringent end and he does not say this because they do not see the bitter end coming any time soon. Yet as the men leave this going off, they head on their long walk and one group sits down to eat lunch. They hear a broadcast from the Emperor that seems to induce a state of defeat in all of the soldiers and makes them as if a cat has their tongue. They are left speech less and "When it was finished, they sat for a while in silence" (13). The soldiers continue to sit in silence and they suddenly decide to bequeath their bamboo spears for the farmer to ameliorate the relationship because they freely used his veranda. The reader can assume here that what the Emperor said is that the bomb had been dropped and the ending of the war has started and that Japan is no longer fighting. The soldiers decide to give away their bamboo spears because they no longer have a use for them. These spears symbolize their side in the war a...

Short Story Essay Example | Topics and Well Written Essays - 500 words

Short Story - Essay Example The journey represents a necessary testing of his faith, but the fear expressed by his wife Faith indicates there is a hidden peril in undertaking such a journey. Her warning, â€Å"may you find all well when you come back† (293), seems to indicate the peril does not apply strictly to Goodman Brown as he sets off on his journey, but for Faith as well as she is left behind in the darkness. In this solitary journey, Hawthorne indicates that the doctrine of purposefully seeking challenges to a faith already weakened by church dictates is a highly dangerous proposition with the capability of leading many men and women to their dooms rather than their salvation. This concept that the experience is leading to doom rather than salvation is defined more as the story progresses and Goodman Brown goes deeper into the darkness of the forest. The people that Young Goodman Brown sees and hears as he makes his way to the heart of the forest proves to him that the human soul is beyond redemption, regardless of their good works performed in the light of day, such as â€Å"a female figure on the path, in whom Goodman Brown recognized a very pious and exemplary dame, who had taught him his catechism in youth, and was still his moral and spiritual adviser, jointly with the minister and Deacon Gookin† (295). It is witnessing of the meeting between the woman and his companion who is presented as the devil, that first opens Young Goodman Brown’s eyes to the idea that the people he has considered so good in his lifetime are as full of sin and corruption as anyone. Throughout his journey, he loses some heart, but determines to hold fast to his Faith and return home. However, when he hears the voices of the villagers in a passing cloud, along with the sound of his own Faith being carried along with them, he gives in altogether and determines to find out what lies at the end of the path. Crying â€Å"my Faith is gone!†,

Strategy,Strategic planning and the tradtional steps to build an Essay

Strategy,Strategic planning and the tradtional steps to build an organizational strategic plan,Strategic management and Competititve Strategy - Essay Example On the other hand, strategic planning is the process through which an organization defines the strategy to achieve major, as well as minor goals. In other words, strategic planning is the directing and the making of crucial decisions that concern the allocation of the available resource as per the institutions strategy. The strategic plan also involves the control process of management as a way of implementing the decisions that encompass the strategic plan. The traditional planning method of building an organizations strategy comprises several steps. However, the tradition style of strategy planning omits the step of innovative thinking which to some works of research is the most important aspect of strategic planning is innovative thinking. It is significant also to state that the approach to strategic planning varies given the unique features of every organization. The unique features may include the purpose of every institution, the culture of each organization, the environment and immediate surroundings and the history of other plans; whether they were successful or not. The first step in strategic planning is the identification of the purpose of the planning process. The procedure makes up the mission statement. The step tends to put forward the reason behind the existence of the firm. The needs of the client makeup the basic purpose of the organization and thus are an outline in the first step. The second step enumerates the vision of the organization. The step’s main focus is the description of the future state of the business entity and the state of the clients of the organization in the future. The third step is the establishment of mandatory goals that the institution must reach in an attempt to achieve the set down goals as per the organization’s mission and vision. The step also tries to give answers for the prevailing challenges that the organization is undergoing through in its operations. The

Classroom Management - Setting Expectations Assignment

Classroom Management - Setting Expectations - Assignment Example 2. Students who miss a day of school should see the Make-Up Work Folder located on the bookshelf next to the pencil sharpener. In this folder, students can find a detailed list of what notes and activities they need to make up. Handouts will be in the folder, but students must borrow notes from another student and copy them by hand to their notebook. Missed assignments are due within 3 school days of the student's return. 3. Required daily materials include a black or blue pen, a pencil, a designated 3-ring binder, and the course textbook. Any other daily materials will be listed on the classroom board, so students can view them as they enter the room and get any required materials before the bell rings. 4. Homework will be assigned daily Monday through Thursday and due at the beginning of class, whether the class reviews it then or later. All work is to be original. Some assignments will be based on completion; others will be graded item by item. 5. Students will use a 3-ring binder dedicated to this course to collect notes, maps, graphic organizers, and other classroom materials. Each item in the notebook, regardless of its type, will be called a document and given a consecutive number. The notebook will be collected and graded based on completion once each grading period and constitutes a large part of students' daily work grade. To communicate these standards to students, verbal and graphic methods should both be used. Also, the plan has to be communicated to parents as well as students (Wong, 1991, p. 170). Graphic methods include writing the rules and procedures for students on handouts that they include in their class notebook, as well as posting the rules on the classroom wall. Parents will be asked to read the rules and procedures established for the class, and then sign a note confirming they have knowledge of them. During the first days of class, students will hear explanations of the procedures and practice them (Wong, 1991, p. 177). To implement standard 5, regarding the class notebook, the teacher should produce samples of notebooks from previous years for students to view, and explain the different types of documents to be included. If possible, handing out a table of contents beforehand helps students' notebooks stay organized. The teacher must emphasize when documents for the notebook are being made, and differentiate them from daily class work that would be handed in. Consistent reinforcement during the first weeks will help students remember to include all necessary documents in the class notebook, allowing them to score a high grade on their daily work. Establishing high expectations for students provides them the immediate benefit of improved academic performance and allows them to realize their potential. Reference Wong, H. K. The first days of school: How to be an effective teacher. Sunnyvale, CA: Harry K. Wong Publications,

Can Alternative Energy Replace Fossil Fuels An Environmental Sciences Essay

Can Alternative Energy Replace Fossil Fuels An Environmental Sciences Essay At the beginning of the 21st century people started to realize that fossil fuels are not renewable and they are consumed too quickly so people believe that there will not be a source for future generations. Activists try to tell people about the consequences of lack of energy in terms of economy or environment, so consciousness of the situation increases each day with the help of activists. However, the public and also the government do not do anything to amend this situation. Professor Emeritus of History, Geography, and American Studies at the University of Texas, Alfred W. Crosby asserts that Alternative sources of energy can become a satisfactory substitute for fossil fuels such as coal, oil, petroleum and diesel if we put as much effort and genius in the effort as we did in producing the first atomic bomb(alternativeenergy.procon.org , para 3). However some others believe that alternative energy cannot meet our need sufficiently. Also its hard to find a suitable place and the hi gh technology to build this kind of structure. There are both pros and cons about using alternative energy which makes it difficult to find the most reliable way, however considering all these various approaches, we can conclude that fossil fuels are more harmful. There are many type of carbon based source which contain huge amount of energy such as coal, oil, natural gas. They are most common source to create energy. Especially in Turkey almost all energy comes from fossil fuels (%99.6). There are some specific places to produce such as Zonguldak for coal or Batman for oil. Underground coal mining sector very taught because working condition is disaster but, people have to work this job because of unemployment. However coal mining have enormous dangerous for health because it cause lung disease. Also cause deaths due to underground coal-mining accidents have been recorded officially since 1941, and a total of 3094 deaths were reported between 1941 and 2003(Kucuker,1). Although this kind of evidence, both government and companies not take any precaution about disasters. Almost the same situation happens in Batman which has most of oil source in Turkey. Some worker suffer from similar problem like health and condition, because they do not know their right in terms of both health and safety even if they are aware of their right companies employ worker on daily-bases so they can not seek their right consequently companies exploit worker easily. In the beginning of industrial age, countries used fossil fuels for their own development without thought about its effect on people and the environment. They also ignored pollution and damage to the environment but this careless behaviour has caused irreversible consequences such as greenhouse effect of burning fossil fuels traps the concentration of carbon dioxide so this also increase heat as a result global warming occur. Therefore people should work together to establish non-governmental organizations to prevent violation and unnecessary usage, because the world supply will not be enough for the next generation. Professor of Massachusetts Institute of Technology, M. S. Dresselhaus also emphasised that fossil fuels currently supply most of the worlds energy needs, world reserves of oil are about 1.61014   (11012  barrels). World consumption is about 1.21010  a day. World reserves of natural gas are about 1.41014  m3; gross production of gas is about 2.41012  m3  per y ear. World coal reserves are about 9.11011  tonnes; annual consumption is about 4.5109  tonnes per year. However unacceptable their long-term consequence, he assert that the supplies are likely to remain adequate for the next few generations. Scientists and policy makers must make use of this period of grace to assess alternative sources of energy and determine what is scientifically possible, environmentally acceptable and technologically promising. Briefly fossil fuels such as coal, oil, natural gas, nuclear power supply most of the worlds energy needs in today world but they are not adequate for future generation without alternative energy. The world has many alternative energy sources such as wind, solar, geothermal, hydroelectric, and bio fuels are possible energy type which can replace fossil fuels. Like fossil fuels these energy types have several advantages and disadvantages. Wind and solar power cause no pollution and are renewable and also wind and solar power are free. The only cost of solar and wind power is the installation and construction of the structure. Nevertheless, both wind and solar energy is inconsistent. It means wind intensity or sunny weather can change. Moreover geothermal energy built upon steam power so they drill holes in the steamy area and steam caused shoot up and drive turbines. Geothermal central should build correctly otherwise harmful gases and mineral can be released. Furthermore, hydroelectric central work with the help of accumulation of water so energy production is constant. However construction of dam is very expensive and sometimes especially in Turkey dam can damage historical p lace like Hasankeyf in the east of Turkey. Lastly like wind and solar power bio fuels is renewable. Ethanol is the main element of creating energy which is made from corn. It decreases the usage of gas but cost of conversion very expensive. In addition, Some countries realize the variety of alternative energy and pay attention to these. Spain and Germany are very serious about creating alternative energy. They use many kind of alternative energy but lost of countries just use hydroelectrical energy in the name of alternative energy. However they do not realize that for example solar energy more powerful than hydroelectrical energy. Dieter Eissel assert that the sun radiates 174 peta-watts (PW). Of this, about 30 percent is re ¬Ã¢â‚¬Å¡ected back to space, while the rest is absorbed by atmosphere, clouds, oceans and land masses. The total volume of radiation absorbed by oceans and lands reaches up to 89 PW. Therefore, solar energy can provide 2,850 times more energy than current world demand. In comparison, the multiple for hydro power is 3, 5 for geothermal, 20 for biomass, and 200 for wind energy (Fischedick, 2000). This means that all nations need the solar radiation of just one day to meet their energy demands for a whole year. However, settle that kind of energy source is very expensive and little utopian. Nevertheless still reducing fossil fuels help prevent the pollution. According to one of the most comprehensive plans for future sustainable energy provision launched in June 2010 by Greenpeace and the European Renewable Energy Council (EREC), a sustainable World Energy Outlook provides a detailed practical blueprint for cutting carbon emissions while achieving economic growth by replacing fossil fuels with renewable energy and energy efficiency (Eissel, 4). Also, there are some kinds of energy types which are related to fossil fuels but not that much harm such as natural gas and nuclear power. Natural gas release methane gas instead of carbon dioxide and methane gas does not cause greenhouse effect it increases the amount of natural gas reserves a little bit higher than fossil fuels. Nuclear power creates a huge amount of energy however risk also very high because if plants accidentally release something its damage may be catasrophic. In the end although fossil fuels have the possibility of least harm to the environment is still a risk. Therefore alternative energy must be encouraged by government and the public. Otherwise countries will start to fight each other because of lack of resource of fossil fuel in fact they already start to fight as resource become limited and countries may occupy an oil-rich country under the name of peace or some unethical reason to take control of oil-reserves. On the other hand, some people claim that the world has enough fossil fuel supplies for at least 2-3 decades. They think that this issue not of great urgency. At the same time they believe alternative energy is not sufficient and enough to meet peoples needs. To exemplify, gas is much more efficient than electrical energy and also filling the cars petrol tank quicker than charging an electrical car. Critics also state that wind power or solar power is not easy to construct everywhere. They can only be built in a suitable place to be efficient. For instance wind turbines  must be built in a windy area to create energy, this means where wind turbines can be constructed is a little restricted. Likewise solar energy is useful in countries which have many hours of direct sunlight. In this situations, as the cost of construction increase also the efficiency decrease. Taking all these points into consideration, we can arrive at the conclusion that alternative energy should be a convenient energy source for future generation, because there is no other option for future generation nobody can claim that fossil fuels will last forever, this generation should regulate the usage alternative energy and also pay attention to the environment. Otherwise fossil fuel become most valuable things in the world and lots of people not allow or afford to benefit from it. Work Cited http://alternativeenergy.procon.org Dresselhaus, M.S., and I.L. Thomas. Alternative energy technologies.  Nature  414.6861 (2001): 332.Academic Search Complete. EBSCO. Web. 23 Dec. 2010. Kucuker, Hudaverdi. Occupational fatalities among coal mine workers in Zonguldak, Turkey, 1994-2003.  Occupational Medicine  56.2 (2006): 144-146.  Environment Complete. EBSCO. Web. 23 Dec. 2010. Park, Sang-Chul, and Dieter Eissel. Alternative Energy Policies in Germany with particular Reference to Solar Energy.  Journal of Contemporary European Studies  18.3 (2010): 323-339.  Academic Search Complete. EBSCO. Web. 23 Dec. 2010. Fischedick, M. ,  Langniss, O. and  Nitsch, J. (2000)  Nach dem Ausstieg-Zukunftskurs Erneuerbare Energie  Hirzel-Verlag , Stuttgart

Comparing the Role of Women in Indian Camp and Shiloh Essay -- compari

Role of Women in Indian Camp and Shiloh  Ã‚     Ã‚  Ã‚   The women of "Indian Camp" experience a life much different from the woman in "Shiloh." Ernest Hemingway wrote "Indian Camp" giving the women a definite role in their families while Bobbi Ann Mason wrote "Shiloh" leaving the woman’s definite family role ambiguous. Because they are responsible for the birth of the babies, the Native American women of the preceding story are the nurturers as opposed to the men. The women accept their roles and partake in their duties without any protest. On the other hand, Norma Jean’s role is not as traditional compared to the other women’s since she and Leroy have no children, she basically lives alone, and she maintains a job. While the Native American women and Norma Jean live different lives, they share the same problem of enduring the men’s ignorance to their needs. However, as the story progresses, Norma Jean realizes she wants to move on in her life, so she does not accept her situation. The Native Ameri can women continue their lifestyle not because they choose to be submissive, but because they know no other way. The women of the two stories lead totally different lives in that the Native American women accept their situation, assume submissive behavior, and endure the ignorance of men, while Norma Jean does not accept her situation, assumes assertive behavior, and does not put up with the ignorance of her husband. Not being exposed to Norma Jean’s independent way of life, the Native American women accept their lives of nurturing and care taking. The doctor’s visit to the Indian camp shows only women helping with the delivery of the baby. As they help the doctor, the men sit up the road away from all the commotion. No signs of resent... ...ver the period of his absence, Norma Jean develops into a stronger person from being on her own. Having Leroy home makes her realize she needs to move on and employs her assertiveness to get out of the situation. Although they remain loyal to their duties through all of the drudgery, the Native American women are strong because they lead a very important role in the family. Norma Jean also proves herself to be strong as she leaves her husband to move on to achieve more in her life. The women share different experiences, but they all exhibit strength in being the way they want to be. Works Cited Hemingway, Ernest. "Indian Camp." In Out Time. New York, Scribner’s, 1955. 16,17. Mason, Bobbi Ann. "Shiloh." Literature: An Introduction to Fiction, Poetry, and Drama. Sixth edition. Eds. X.J. Kennedy and Dana Gioia. New York: Harper Collins, 1995. 495, 496, 500. Comparing the Role of Women in Indian Camp and Shiloh Essay -- compari Role of Women in Indian Camp and Shiloh  Ã‚     Ã‚  Ã‚   The women of "Indian Camp" experience a life much different from the woman in "Shiloh." Ernest Hemingway wrote "Indian Camp" giving the women a definite role in their families while Bobbi Ann Mason wrote "Shiloh" leaving the woman’s definite family role ambiguous. Because they are responsible for the birth of the babies, the Native American women of the preceding story are the nurturers as opposed to the men. The women accept their roles and partake in their duties without any protest. On the other hand, Norma Jean’s role is not as traditional compared to the other women’s since she and Leroy have no children, she basically lives alone, and she maintains a job. While the Native American women and Norma Jean live different lives, they share the same problem of enduring the men’s ignorance to their needs. However, as the story progresses, Norma Jean realizes she wants to move on in her life, so she does not accept her situation. The Native Ameri can women continue their lifestyle not because they choose to be submissive, but because they know no other way. The women of the two stories lead totally different lives in that the Native American women accept their situation, assume submissive behavior, and endure the ignorance of men, while Norma Jean does not accept her situation, assumes assertive behavior, and does not put up with the ignorance of her husband. Not being exposed to Norma Jean’s independent way of life, the Native American women accept their lives of nurturing and care taking. The doctor’s visit to the Indian camp shows only women helping with the delivery of the baby. As they help the doctor, the men sit up the road away from all the commotion. No signs of resent... ...ver the period of his absence, Norma Jean develops into a stronger person from being on her own. Having Leroy home makes her realize she needs to move on and employs her assertiveness to get out of the situation. Although they remain loyal to their duties through all of the drudgery, the Native American women are strong because they lead a very important role in the family. Norma Jean also proves herself to be strong as she leaves her husband to move on to achieve more in her life. The women share different experiences, but they all exhibit strength in being the way they want to be. Works Cited Hemingway, Ernest. "Indian Camp." In Out Time. New York, Scribner’s, 1955. 16,17. Mason, Bobbi Ann. "Shiloh." Literature: An Introduction to Fiction, Poetry, and Drama. Sixth edition. Eds. X.J. Kennedy and Dana Gioia. New York: Harper Collins, 1995. 495, 496, 500.

Chemistry Extended Essay Essay

To investigate the effect of 2-bromo-2-methyl propane concentration and temperature of the system on the rate of reaction of solvolysis of 2-bromo-2-methyl propane in 90% ethyl alcohol Done by: Habib Iscandar Hinn Friend’s Boy’s School June 22, 2007 To investigate the effect of 2-bromo-2-methyl propane concentration and temperature of the system on the rate of reaction of solvolysis of 2-bromo-2-methyl propane in 90% ethyl alcohol Introduction: The major product of the solvolysis of t -butyl chloride in 70 % water – 30 % acetone is t-butyl alcohol, with a small amount of isobutylene being formed as a by product And this is with accordance of first order kinetic and suggests a two step mechanism in which the rate determining step consists of the ionization of t-butyl chloride, and in this mechanism a carbonium ion is formed as inter- mediate and this bonds immediately to near by nucleophile (in this case nucleophile is a neutral molecule) the initial product is t-butyl carbonium ion. â€Å"Note1: if the nucleophile is neutral the product will be charged since the leaving group takes both bonding electrons away with it† So chemists have proposed to general types of mechanism: 1- Nucleophilic substitution Sn1 The ionization step in a Sn1 reaction is endothermic and much slower than the exothermic neutralization of carbonium ion by a nucleophile. And so the rate determining step being the unimolecular ionization of the t-butyl chloride equation 4, and as a result, the overall rate of reaction is not affected by changes in the concentration or kinds of nucleophilic reagents present. â€Å"Note2: the factor which determines the mechanisms employed is typically the nature of the substrate it self and not the particular nucleophile† â€Å"Note3: if the sum of the energy of the product is lower than the energy of the reactant the reaction is exothermic, and if the product have higher energy than the reactant the reaction is endothermic.† 2- Elimination E1 (elimination unimolecular) And because t-butyl chloride acts as a Lewis acid (an electrophile) and combines with a nucleophile to give a substitution product, so the major product of the solvolysis of t-butyl chloride in water-acetone solvent is t-butyl alcohol. (â€Å"Note4†: electrophile: an electron deficient atom, ion or molecule that as affinity for an electron pair, and will bond to a base or nucleophile.) (â€Å"Note5 â€Å": nucleophile: and atom, ion , or molecule that has an electron pair that may be donated in forming covalent bond to an electerophile.) Evaluating the mechanism: The only reactant that is undergoing change in the rate determining step is t-butyl chloride and so such reactions is a unimolecular and follow a first order equation (Sn1, E1). â€Å"This means that the rate of the reaction varies directly with the concentration of t- butyl chloride†. And since nucleophilic only participate in the fast second step, so their relative molar concentrations rather than their nucleiophilities are the primary product – determining factor, and by using nucleophilic solvent like water, so its high concentration will assure that alcohols are the major product, and because water have a high dielectric constant (e=81) so water molecule tend to orient them-selves in such a way as to decrease the electrostatic forces between ions. And an important factor is the salvations which refer to water molecules ability stabilize ions by encasing them in a sheath of weakly bonded solvent molecules: 1- Anions are solvated by hydrogen – bonding, 2- Cations are solvated by nucleophilic sites on water molecule (oxygen). And in this case of t-butyl carbonium ion the nucleophiles form strong covalent bond to carbon and converting the intermediate to a substitution product. The reaction mechanism is a sequential account of each transition state and intermediate in a total reaction, the over all rate of reaction is determined by the transition state of highest energy in the sequence, so the rate determining step is the rate determining step for both the Sn1 and E1 for t – butyl chloride. (â€Å"Note 6†: the water soluble organic solvent acetone is used to keep a reasonable concentration of t-butyl chloride in solution) The balance equation for t-butyl chloride solvolysis in water-acetone solvent is: The effect of concentration on the solvolysis of t-butyl chloride in 70 %water – 30 %acetone solvent. As the reaction proceeds the solution becomes increasingly acidic until all of the t -butyl chloride has reacted and all HCl that can form has formed. So we will monitor the reaction by allowing HCl formed to neutralize a predetermined amount of NaOH. An indicator dye (bromo-phenol blue) will change color when the NaOH has been neutralized, and clocking of the reaction should begin at the instant. So according to kinetic measurements: Rate of reaction = K [t – butyl chloride] Where K is the specific rate constant in S -1 and [t – butyl chloride] is the concentration of t-butyl chloride in M. Our kinetic measurement will depend on the determination of the amount of HCl produced by the reaction, so by monitoring the color change of the acid – base indicator, we will determine the time required for 10% of t-butyl chloride to hydrolyze by having 10 % as much NaOH present as T-butyl chloride. Rate = – d [Rcl] dt ; Where Rcl = -dt [Rcl] = K [Rcl] dt Rearranging, d [Rcl] = -K dt [Rcl] And integrating for t=0 to t=t will give; = Ln [Rcl] t – Ln [Rcl] 0 = – Kt – 2.303 Log [Rcl] 0 = – Kt [Rcl] t 2.303 Log [Rcl] 0 = Kt [Rcl] t Where [Rcl] 0: is the molar concentration at time t = 0 [Rcl] t: is the molar concentration at time t = t Two methods to calculate K 1- since the equation Kt = 2.303 Log [Rcl] 0 [Rcl] t Is an equation of a straight line (y=mx+b) with slope k. and intercept =0, a plot of 2.303 log [Rcl] 0 / [Rcl] t versus t should yield a straight line with slope k. 2- if the solvolysis reaction run to 10% completion Then, [Rcl] = 0.90 [Rcl] 0 Kt = 2.303 Log [Rcl] 0 = 2.303 log (1.11) 0.90 [Rcl] 0 And therefore, K = 0.104 T So by finding the value of K and compensate it in the rate of reaction equation â€Å"Rate = K[Rcl]† where the concentration of Rcl is known we can calculate the value of the rate of reaction and we will see it’s effect on the solvolysis of t – butyl chloride in 70% water – 30 % acetone solution. The effect of temperature on the solvolysis of t -butyl chloride in 70%water – 30%acetone solvent. In nearly every instance an increase in temperature causes an increase in the rate of reaction, â€Å"because the total fraction of all of the t – butyl chloride 1molecules having energies equal to or greater than activation energy (Ea) Corresponds to the shaded portion of the area under the curve increases by increasing the temperature† and by comparing the area for two different temperature, we see that the total fraction of t- butyl chloride molecules with sufficient kinetic energy to undergo reaction increases with increasing temperature and consequently, so does the reaction rate. â€Å"Note7: changing the concentration affects the rate of reaction changing the temperature affects the rate constant as well as the rate.† By finding the values of reaction rate constant K for different concentration of t-butyl chloride and different reaction temperature, we will find the effect of temperature on the solvolysis of t-butyl chloride in water acetone solvent. Quantitatively, K (s-1) is related to Ea and T by the equation K1 = Ae-Ea/RT1 †¦Ã¢â‚¬ ¦1 Ea is the activation energy, in joule / mole. (Jmol-1) A is a proportionality constant, in s-1 R is the gas constant = 8.314 Jmol-1K-1 e is the base of the natural logarithms. T is temperature in Kelvin. This relation ship is known as Arrhenius equation We measure Ea by taking the natural logarithm of eq.1 Ln K = ln A – Ea RT Thus, a plot of ln k versus 1/T gives a straight line whose slope is equal to -Ea/R and whose intercept with coordinate is ln A â€Å"Note8: Ea is the activation energy, a constant characteristic of the reaction† We can calculate the rate constant at some specific temperature if Ea and K at some other temperature are known. For any temp. T1 (known), Ea (known), K1 (known) K1 = A e -Ea/RT1 For any other T2 (known); (K2 unknown) K2 = A e -Ea/RT2 By dividing K1 over K2 K1 = A e -Ea/RT1 K2 A e -Ea/RT2 Taking natural logarithm of both sides, we get Ln K1 = Ea (1/T2 – 1/T1). K2 R Or in common logarithms (base 10 logarithms) gives: Log K1 = Ea (1/T2 – 1/T1) K2 2.303 R And by finding the value of K2 we will be able to find the rate of reaction at T2 and we will find the effect of temperature on the rate of solvolysis of t – butyl chloride in 70 % water – 30 % acetone solution. By finding the values of reaction rate constant K for different concentration of t-butyl chloride and different reaction temperature, we will find the effect of concentration and temperature on the solvolysis of t-butyl chloride in water acetone solvent. Procedure: Part A: the effect of concentration on the rate of solvolysis of t – butyl chloride in 70%water – 30%acetone solvent. a- Experimental procedure: to measure the time necessary for 10 % solvolysis of t – butyl chloride (0.1 M concentration) in 70 % water – 30% acetone solvent at room temperature. A, a, I:- 1- Prepare 500 ml of 0.1 M t- butyl chloride in acetone only and put it in an Erlenmeyer flask and label it #1. 2- Prepare 100 ml of 0.1 M NaOH solutions (in water) and put it in an Erlenmeyer and label it #2. 3- Using a burette take 30 ml of the solution in flask #1 and put it in another Erlenmeyer and label it #3. 4- By a graduated pipette take 3 ml of sodium hydroxide 0.1 M in an Erlenmeyer flask and label it #4. 5- Using a graduated cylinder measure 67 ml of distilled water added to an Erlenmeyer flask #4. 6- Add two drops of Bromo-phenol blue indicator to flask #4. A, a, II:- 1- Add quickly the solution in Erlenmeyer flask #4 to solution in flask #3 and start the stop watch to count for time in seconds. 2- Swirl the mixture and after one or two seconds immediately pour the combined solutions back into Erlenmeyer flask #4 to minimize the errors in the results. 3- The color of the mixed solutions is blue, so continue swirling the solution in Erlenmeyer flask #4 till the instant color of the solution start changing to yellow, then we stop the stopwatch and record the time. 4- Repeat the procedure at least three times and calculate the average. 5- Tabulate the results in record A. b- Experimental procedure: to measure the time necessary for 10 % solvolysis of t – butyl chloride (0.2 M concentration) in 70 % water – 30% acetone solvent at room temperature. A, b, I:- 1- Prepare 500 ml of 0.2 M t- butyl chloride in acetone only and put it in an Erlenmeyer flask and label it #1. 2- Prepare 100 ml of 0.1 M NaOH solutions (in water) and put it in an Erlenmeyer flask and label it #2. 3- Using a burette take 30 ml of the solution in Erlenmeyer flask #1 and put it in another Erlenmeyer flask and label it #3. 4- By a graduated pipette take 3 ml of sodium hydroxide 0.1 M in an Erlenmeyer flask and label it #4. 5- Using a graduated cylinder measure 67 ml of distilled water added to an Erlenmeyer flask #4. 6- Add two drops of bromo-phenol blue indicator to Erlenmeyer flask #4. A, b, II:- 1- Add quickly the solution in an Erlenmeyer flask #4 to solution in flask #3 and start the stop watch to count for time in seconds. 2- Swirl the mixture and after one or two seconds immediately pour the combined solutions back into an Erlenmeyer flask #4 to minimize the errors in the results. 3- The color of the mixed solutions is blue, so continue swirling the solution in Erlenmeyer flask #4 till the instant color of the solution start changing to yellow, then we stop the stopwatch and record the time. 4- Repeat the procedure at least three times and calculate the average. 5- Tabulate the results in record A. Part B: the effect of temperature on the rate of solvolysis of t – butyl chloride in 70%water – 30%acetone solvent. a- Experimental procedure: to measure the time necessary for 10 % solvolysis of t – butyl chloride (0.1 M concentration) in 70 % water – 30% acetone solvent at zero Celsius degree. B, a, I:- 1- Prepare 500 ml of 0.1 M t- butyl chloride in acetone only and put it in an Erlenmeyer flask and label it #1. 2- Prepare 100 ml of 0.1 M NaOH solutions (in water) and put it in an Erlenmeyer flask and label it #2. 3- Using a burette take 30 ml of the solution in Erlenmeyer flask #1and put it in an Erlenmeyer flask and label it #3. 4- By a graduated pipette take 3 ml of sodium hydroxide 0.1 M in an Erlenmeyer flask and label it #4. 5- Using a graduated cylinder measure 67 ml of distilled water added to Erlenmeyer flask #4. 6- Add two drops of bromo-phenol blue indicator to Erlenmeyer flask #4. B, a, II:- 1- Suspend the Erlenmeyer flasks in a water bath full with ice and water, allowing the temperature of the Erlenmeyer flasks and their contents to equilibrate for ten minutes. 2- Adding quickly the solution in Erlenmeyer flask #4 to solution in Erlenmeyer flask #3 and start the stop watch to count for time in seconds. 3- Swirl the mixture and after one or two seconds immediately pour the combined solutions back into Erlenmeyer flask #4 to minimize the errors in the results. 4- The color of the solution after that will become blue, so continue swirling the solution in Erlenmeyer flask #4 till the instant color of the solution start changing to yellow we stop the stop watch and record the time 5- Repeat the procedure at least three times and calculate the average. 6- Tabulate the results in record B. b- Experimental procedure: to measure the time necessary for 10 % solvolysis of t – butyl chloride (0.1 M concentration) in 70 % water – 30% acetone solvent at a temperature greater than room temperature by ten degrees. B, b, I:- 1- Prepare 500 ml of 0.1 M t- butyl chloride in acetone only and put it in an Erlenmeyer flask and label it #1. 2- Prepare 100 ml of 0.1 M NaOH solutions (in water) and put it in an Erlenmeyer flask and label it #2. 3- Using a burette take 30 ml of the solution in Erlenmeyer flask #1 and put it in an Erlenmeyer flask and label it #3. 4- By a graduated pipette put 3 ml of sodium hydroxide 0.1 M in an Erlenmeyer flask and label it #4. 5- Using a graduated cylinder measure 67 ml of distilled water added to Erlenmeyer flask #4. 7- Add two drops of bromo-phenol blue indicator to flask #4. B, b, II:- 1- Suspend the flasks #3 and #4 in a water bath full with ice and water, allowing the temperature of the flasks and their contents to equilibrate for ten minutes.(to reach the temperature of the water bath) 2- Adding quickly the solution in flask #4 to solution in flask #3 and start the stop watch to count for time in seconds. 3- Swirl the mixture and after one or two seconds immediately pour the combined solutions back into flask #4 to minimize the errors in the results. 4- The color of the mixed solutions is blue, so continue swirling the solution in flask #4 till the instant color of the solution start changing to yellow we stop the stopwatch and record the time 5- Repeat the procedure at least three times and calculate the average. 6- Tabulate the results in record B. Record A Run number Temperature Time of 10 % reaction Average time / seconds Record B Run number Temperature Time required for 10% reaction Average time/seconds Average time/ seconds References; * E. Brady, James. E. Humiston, Gerard., General Chemistry Principles and Structure, second edition, SI version, john Willy and sons, Inc. * Brewester, Vaderwerf and McEwen. â€Å"Unitized Experiments in Organic Chemistry†, 3rd Ed. * Streitwieser, Andrew. H. Heathcock, Clayton. Introduction to Organic Chemistry. * H. Reusch, William. An Introduction to Organic Chemistry. * J. Laidler, Keith. Chemical kinetics. 2nd ed. * Search engines that where used: o www.google.com o www.yahoo.com * Goldwhite, Harold. R. Spielman, John. College Chemistry, 1984

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